Uniquely for weapon upgrade paths, the Chaos path scales with humanity (up to 10). This, along with the lack of stat scaling, ultimately means that Chaos weapons have an inferior damage potential in the long run.
This makes it a good choice for lower levels.
The Chaos path adds Fire Damage to a weapon, but removes all stat scaling bonuses. Creation of a Chaos weapon requires a +5 Fire weapon (which in turn requires a standard weapon +5), Red Titanite Chunks for upgrading to +4 and a Red Titanite Slab for upgrading to +5, as well as the requisite souls. Vamos gains the ability to ascend weapons down the Chaos path after receiving the Chaos Flame Ember.
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